Silicon Nitride Deposition (SiN)

SiN Image courtesy of:
Sensitech (IMO) Wetzlar
Hr Castricher, Dr Schultheiss
  • PECVD 
  • ICP CVD 
  • Ion Beam 
  • Notes 
  •  

PECVD of Silicon Nitride 

  • Rate: 5 - 100 nm/min
  • Good uniformity over up to 6” wafer
  • The refractive index can be adjusted from 1.77 to 2.54

 

PECVD of SiN - Ammonia free

  • Deposition rate 7 - 12 nm/min
  • Refractive index 2.00
  • Refractive index variation (across table) < ± 1%
  • Refractive index variation (run to run) < ± 1%

Inductively Coupled Plasma Chemical Vapour Deposition SiN

  • Uniformity   ± 2 - 4  % over one full batch
  • Deposition rate 10 - 15 nm/min, max 100 nm/ min
  • Refractive Index typically 2.0, but fully controllable 1.8 - 2.5

 

 

Ionfab 300Plus

Silicon Nitride (Si3N4) Reactive Ion Beam Deposition (RIBD)

Process Specification
Si3N4 RIBD in the Ionfab300Plus (LC)

  • Pre-clean: 35cm source can pre-clean up to 200mm substrates
  • Deposition Gases: Ar, N2
  • Up to 200mm wafers
  • Summary performance data:

 Chamber base pressure <3e-7 Torr 
 Load lock base pressureb <1e-5 Torr

a. After 12 hours bake out at 80°C.
b. Load lock pumps down to 6E-5Torr in less than three minutes. It takes less than five minutes from sample loading i.e. from the load lock to process platen with load lock pump down sequence.


Process specification

1. Si3N4 deposition with rotation and adjustable tilt.

Parameter/Process Si3N4 dep
Target  (size=200mm) Si3N4
Gas chemistry Ar+N2
Deposition rate [nm/min] 0.5 to 4nm/min
Uniformity over 8” [±%]1, 2 <±2%
Reproducibility [±%] <±3
Stress (compressive)2 <500MPa

Notes: 

1. With 5mm edge exclusion
2. Stress and uniformity value are guaranteed for deposition rates up to 50% of maximum rate

Additional Notes:

1. The data given above applies to High Frequency films. 
2. Accuracy of measurement of low stress values is highly dependent on:

  • the accuracy of wafer curvature measurement both before and after film deposition
  • the quality and pre-stressing of wafers used for stress measurements
  • and requires a thick film (>5000Å) to produce a detectable/accurately measurable wafer curvature

3. Results given above apply to Silicon substrates.
4. Cleaning and conditioning of the chamber may be required when switching between processes, to obtain optimum repeatability. A minimum conditioning thickness of 2000-3000A is recommended. Further advice on chamber cleaning/conditioning strategies will be provided by OIPT based on customers’ applications and intended use of system.
5. Standard definitions of uniformity given below:

Within wafer uniformity is measured in a five point pattern: Run-to-run uniformity (reproducibility) is calculated from average wafer uniformity in 5 consecutive runs.
 

 

 

 

For refractive index uniformity is calculated as:

 

 

 

For refractive index uniformity is calculated as:

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